Direct Production of Lower Olefins from CO 2 Conversion via Bifunctional Catalysis
Yong Han, Peng Gao, Shanshan Dang, Shenggang Li, Xianni Bu, Ziyu Liu, Minghuang Qiu, Chengguang Yang, Hui Wang, Liangshu Zhong, Qiang Liu, Wei Wei, Yuhan Sun
ACS Catal., 2018, 8, 571-578
Direct conversion of carbon dioxide (CO2) into lower olefins (C2=−C4=), generally referring to ethylene, propylene, and butylene, is highly attractive as a sustainable production route for its great s…
Highly Active ZnO-ZrO 2 Aerogels Integrated with H-ZSM-5 for Aromatics Synthesis from Carbon Dioxide
Wei Zhou, Jincan Kang, Kang Cheng, Jiaqing Shi, Cheng Zhou, Qinghong Zhang, Ye Wang
ACS Catal., 2020, 10, 302-310
Bifunctional catalysis coupling CO2 to methanol and methanol to hydrocarbons is a promising strategy for the direct hydrogenation of CO2 into high-value chemicals. However, bifunctional catalysts suff…
Highly Selective Conversion of Carbon Dioxide to Aromatics over Tandem Catalysts
Mingrun Li, Shu Miao, Zelong Li, Jijie Wang, Yuanzhi Qu, Hailong Liu, Can Li
Joule, 2019, 3, 570-583
Conversion of CO2 to aromatics is a promising route to realize the proposal on carbon capture and utilization based on strategic CO2 carbon resource. In this work, CO2 is converted to aromatics with …
Selective conversion of CO2 and H2 into aromatics
Youming Ni, Yong Liu, Zhiyang Chen, Yi Fu, Wenliang Zhu, Zhongmin Liu
Nat Commun, 2018, 9, 3457
Transformation of greenhouse gas CO2 and renewable H2 into fuels and commodity chemicals is recognized as a promising route to store fluctuating renewable energy. Although several C1 chemicals, olefi…
Highly Selective Conversion of Carbon Dioxide to Lower Olefins
Shu Miao, Zelong Li, Jijie Wang, Yuanzhi Qu, Hailong Liu, Chizhou Tang, Zhaochi Feng, Hongyu An, Can Li
ACS Catal., 2017, 7, 8544-8548
Conversion of CO2 to value-added chemicals has been a long-standing objective, and direct hydrogenation of CO2 to lower olefins is highly desirable but still challenging. Herein, we report a selective…
Design of a core–shell catalyst: an effective strategy for suppressing side reactions in syngas for direct selective conversion to light olefins
Li Tan, Fan Wang, Peipei Zhang, Yuichi Suzuki, Yingquan Wu, Jiangang Chen, Guohui Yang, Noritatsu Tsubaki
Chem. Sci., 2020, 11, 4097-4105
The preparation of a Zn–Cr@SAPO capsule catalyst and the two different mass transfer routes over the capsule catalyst and physical mixture catalyst in light olefins synthesis from syngas.
Tandem Catalysis for Hydrogenation of CO and CO2 to Lower Olefins with Bifunctional Catalysts Composed of Spinel Oxide and SAPO-34
Jincan Kang, Kang Cheng, Qinghong Zhang, Ye Wang, Xiaoliang Liu, Mengheng Wang, Haoren Yin, Jingting Hu
ACS Catal., 2020, 10, 8303-8314
Transformation of syngas (H2/CO) and hydrogenation of CO2 into lower olefins are attractive routes for chemical utilization of various carbon resources and CO2, but both suffer from limited product s…
Conversion of Synthesis Gas to Light Olefins: Impact of Hydrogenation Activity of Methanol Synthesis Catalyst on the Hybrid Process Selectivity over Cr–Zn and Cu–Zn with SAPO-34
Alexey V. Kirilin, Joseph F. Dewilde, Vera Santos, Adam Chojecki, Kinga Scieranka, Andrzej Malek
Ind. Eng. Chem. Res., 2017, 56, 13392-13401
Direct conversion of syngas to hydrocarbons occurs over hybrid catalyst mixtures containing methanol synthesis and microporous acid components. In particular, both copper and zinc oxide-based as well…
Size Effects of ZnO Nanoparticles in Bifunctional Catalysts for Selective Syngas Conversion
Feng Jiao, Xiulian Pan, Xinhe Bao, Na Li, Yi Ding, Jingyao Feng
ACS Catal., 2019, 9, 960-966
The oxide−zeolite (OX−ZEO) bifunctional catalyst design concept has shown promising potential for selectivity control in syngas conversion by separating CO activation and C−C coupling onto oxides and…
Syngas to light olefins conversion with high olefin/paraffin ratio using ZnCrOx/AlPO-18 bifunctional catalysts
Junjie Su, Dong Wang, Yangdong Wang, Haibo Zhou, Chang Liu, Su Liu, Chuanming Wang, Weimin Yang, Zaiku Xie, Mingyuan He, Wenqian Jiao, Yingchun Ye, Lin Zhang, Yu Zhao, Hongxing Liu
Nat Commun, 2019, 10, 1297
Direct synthesis of light olefins from syngas (STO) using a bifunctional catalyst composed of oxide and zeolite has attracted extensive attention in both academia and industry. It is highly desirable…